The present invention relates to a method for producing a nonwoven fabric made of cellulose, especially a cellulose solution.
Cellulosic fibers and filaments are formed by spinning a solution of the
cellulose amine oxide solvent followed by leaching in a dilute solution
of water or an aqueous amine oxide to form cellulosic filaments which
can then be cut into staple fibers. This extrusion and coagulation
process is called solution spinning, and the solution spun cellulose
fibers thus produced are generally called "lyocells".
It is possible to make smaller decitex fibres below 1.0 dtex by
stripping the staple fibres. However, high costs and high energy
consumption.
Therefore, the present invention provides a method for producing a
cellulose nonwoven fabric made of fibers, the fiber being formed by
extruding a solution of cellulose, passing it through at least one
spinnerette, and extruding the fibers through the action of a high-speed
airflow. Fine, fine fibers are collected on a surface, and the web is
then solidified on this surface.
The term "gas" includes various kinds of steam such as steam.
The cellulose solution is preferably a cellulose solution using an amine
oxide as a solvent, and is generally a N-oxide tertiary amine,
especially N-methylmorpholine-N-oxide (NMMO). The cellulose solution may
contain as little as 2% by weight of cellulose; however, the solution
preferably contains 4 to 22% by weight of cellulose, with a cellulose
degree of polymerization of 200 to 5,000, more usually 400 to 1,000.
In a preferred embodiment, the cellulose solution contains 15% by weight
of cellulose, 10% by weight of water, 75% by weight of NMMO, and the
cellulose has a degree of polymerization of about 600.
Microfibrils or fibrils formed by fiber refinement are collected on one
surface and then solidified by water (also referred to as
"regeneration") or dilute aqueous amine oxide solution containing up to
20% amine oxide in water.
The gas, preferably air or steam, is blown onto the extruded fibers at a
rate of 125-155°C, preferably about 150°C, at a rate of 250-500 m.s-1
(m/s). The lower the cellulose content in the spinning dope, the lower
the air temperature that can be used. When the cellulose content in the
spinning solution is low, the air temperature can be reduced to nearly
100°C. The gas flow rate should be at least 50 times higher than the
speed at which fibers are extruded from the spinneret, preferably 1,000
to 20,000 times the speed.
The air is blown toward the extruded fiber at an oblique angle,
preferably 15-45[deg.] with respect to the axial direction of the
extrudate, preferably about 30[deg.]. The gas flow can also be skewed at
a second oblique angle with respect to the spinnerette, even if the gas
flow axis and the fiber axis do not intersect, the gas flow is
tangential to the surface of the fiber extrudate.
According to the present invention, there is provided simultaneously an
apparatus for manufacturing a nonwoven fabric containing "lyocell"
fibers, the apparatus comprising a spinning cap for extruding a
cellulose solution during operation; and one or more gas nozzles
equipped therewith The gas flow is directed to the extrudate to make the
extrudate fine and to form fibrils; a support surface is provided to
collect the refined extrudate; regeneration means to coagulate the
fibrils on the support surface. The support surface provided is
preferably a drum surface.
Because the fibrils or fibers are collected on the support surface
before regeneration, the fibers in contact with each other can be bonded
to each other.
Thus, the present invention also provides a "lyocell" nonwoven fabric in which fibers can be bonded together without adhesives.
Hereinafter, the present invention will be described in detail by way of examples with reference to the accompanying drawings.
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